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source: Macmillan Encyclopedia of Chemistry editor: Joseph J. Lagowski publisher: Simon & Schuster Macmillan city: New York year: 1997 volume: 1 first page: 166 last page: 170 isbn: 0-02-897225-2 |
Article Description: Mechanism of electrophilic aromatic substitution (substituent effects on rate and product, methods of catalysis, intermediates). Major types of alkylation (with, without rearrangements); acylation; halogenation; nitration. Synthetic industrial value. Contrast between classic Friedel-Crafts and modern methods. Brief mention of nucleophilic aromatic substitution. [2000 words]