title: Progress in Controlled Radical Polymerization: Mechanisms and Techniques series: ACS Symposium Series editors: Krysztof Matyjaszewski, Brent S. Sumerlin, Nicolay V. Tsarevsky publisher: American Chemical Society city: Washington, DC year: 2012 volume: 1100 first page: 115 last page: 132 isbn: 9780841226999 (Print) 9780841227002 (Online) doi: 10.1021/bk-2012-1100.ch008 |
Abstract: The catalytic activity of a series of homobimetallic ruthenium complexes of the type [(p-cymene)Ru(μ-Cl)3RuCl(L)(L')] [L = C2H4 or a vinylidene ligand (=C=CHR); L' = PPh3, PCy3, or an N-heterocyclic carbene ligand] was determined by investigating the atom transfer radical polymerisation of methyl methacrylate. The results clearly demonstrate that the ligands strongly affect the ability of the ruthenium complexes to favour the occurrence of a well-behaved ATRP.