"Microwave-Enhanced Ruthenium-Catalysed Atom Transfer Radical Additions"

Yannick Borguet, Aurore Richel, Sébastien Delfosse, Alain Leclerc, Lionel Delaude, and Albert Demonceau

journal cover
          source: Tetrahedron Letters
            year: 2007
          volume: 48
      first page: 6334
       last page: 6338
             doi: 10.1016/j.tetlet.2007.07.029

graphical abstract

Abstract: The first monomode microwave-assisted atom transfer radical additions (ATRA) of carbon tetrachloride to various olefins were successfully performed, affording the adducts with almost quantitative yields in less than 10 min at 160 °C.

Keywords: Catalysis, Microwave, Olefins, Radicals and Radical Reactions, Ruthenium and Compounds

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