"Microwave-Assisted Synthesis of Imidazolinium Salts"

Morgan Hans, Albert Demonceau, and Lionel Delaude


journal cover
          source: Polymer Preprints
                  (American Chemical Society,
                  Division of Polymer Chemistry)
            year: 2008
          volume: 49(2)
      first page: 942
       last page: 943

Abstract: The synthesis of imidazolinium salts from N,N'-disubstituted ethylenediamines and orthoesters proceeds briskly under microwave irradiation. The transformation is highly versatile and tolerates a wide range of substituents and counterions. Since the work-up is equally rapid and straightforward, this experimental procedure provides a fast and convenient access to an important class of heterocyclic compounds that may serve as NHC precursors and ionic liquids.


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